Are there infinitely many integers not of the form $n - \phi(n)$?
This is true, as shown by Browkin and Schinzel [BrSc95].
[BrSc95] Browkin, J. and Schinzel, A., On integers not of the form {$n-\phi(n)$}. Colloq. Math. (1995), 55-58.
It follows from a slight strengthening of the Goldbach conjecture that every odd number can be written as $n - \phi(n)$. In particular, we assume that every even number greater than 6 can be written as the sum of two distinct primes, in contrast to the usual Goldbach conjecture that every even number greater than 2 can be written as the sum of two primes.
Erdős has shown that a positive density set of integers cannot be written as $\sigma(n) - n$.
[Er73b] Erdős, P., Über die Zahlen der Form $\sigma (n)-n$ und $n-\phi(n)$. Elem. Math. (1973), 83-86.
A solution to erdos_418 was shown by Browkin and Schinzel [BrSc95] by showing that any integer of the form $2^(k + 1)\cdot 509203$ is not of the form $n - \phi(n)$.
[BrSc95] Browkin, J. and Schinzel, A., On integers not of the form {$n-\phi(n)$}. Colloq. Math. (1995), 55-58.